Physics Maths Engineering

Boron Recovery from Organic Solutions Used in Brine Treatment through a Water Stream






  Peer Reviewed

Abstract

Abstract

This research evaluates the modification of the lithium carbonate (Li2CO3) production process and particularly the boron removal step, which currently employs a recirculated stream. This recirculated stream is a liquor with low boron content but rich in lithium, currently being wasted. In this process, the recirculating stream is substituted with a freshwater stream. Boron is re-extracted from the loaded organic stream to form an input stream for a boric acid process. Under certain operational conditions, the formation of emulsions was observed; due to this, the analysis of emulsion formation involved controlling the pH of each sample, which lead to the development of a procedure to prevent such formations. From this analysis, it was determined that emulsions form in water with pH values below 1.3 and above 6.9. In addition, a speciation analysis showed that the concentrations of the H2BO3− and H+ species influence the formation of emulsions. The mass balance of the process showed that by replacing the recirculated stream, boron recovery of 89% was achieved, without the need to add new stages or equipment.

Key Questions

How do you remove boron from brine?

Boron can be removed from brine by acidifying it to pH 0.1-6.0 and contacting it with an organic extraction medium containing diols with 6-20 carbon atoms.

What are the best solvents for extracting boron?

Effective solvents for boron extraction include 2-ethyl-1,3-hexane diol, isopentanol, isooctyl alcohol, and isodecanol dissolved in aromatic or kerosene solvents.

How efficient is reverse osmosis for boron removal?

Reverse osmosis can remove up to 50% of boron under neutral conditions and nearly 100% under alkaline conditions.

What factors affect boron removal by reverse osmosis?

Key factors include solution pH, initial boron concentration, salinity, temperature, recovery ratio, pressure, and feed flow rate.

How does pH affect boron removal?

Increasing pH generally improves boron removal efficiency for most processes, including reverse osmosis, forward osmosis, and solvent extraction.

What is the best way to recover boron from salt lake brines?

Solvent extraction using monohydric alcohols like isodecanol can achieve over 99% boron recovery from salt lake brines with high magnesium content.